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Microstructure and properties of aluminium-high entropy alloy composites fabricated by mechanical alloying and spark plasma sintering
Materials Today Communications ( IF 3.8 ) Pub Date : 2020-06-25 , DOI: 10.1016/j.mtcomm.2020.101366
Nairan Wang , Bo Wu , Weilong Wu , Jiu Li , Chunhua Ge , Yifan Dong , Lanxiang Zhang , Yan Wang

High-quality aluminium-CuZrNiAlTiW high-entropy alloy (HEA) composites were fabricated by mechanical alloying and spark plasma sintering (SPS). The microstructures, mechanical properties and corrosion resistance of these composites were investigated. The as-milled HEA powders consist of a single body-centered cubic (BCC) solid solution phase. Besides the Al and BCC phases, the NiAl-rich B2 and WAl12 phases were in-situ formed in the sintered composites due to the large concentration gradient of Al between the matrix and HEA reinforcement. Compared to the SPS-ed Al bulk, the Al-HEA composites show higher microhardness and strength, caused by the dispersion strengthening of BCC phase and precipitation strengthening of B2 and WAl12 phases, as well as the serious lattice distortion. The core-shell microstructure in the composite with 10 vol.% HEA (Al10) contributes to its good compression properties with high yield strength and good plasticity. The Al20 composite exhibits a high fracture strength of 544 MPa, owing to the uniform size and distribution of BCC particles. Additionally, W and Ni could improve the stability of protective layer, and thus enhance the pitting resistance of the Al-HEA composites in seawater. The Al10 composite possesses the relatively positive corrosion potential and low corrosion rate, revealing a good general corrosion resistance.



中文翻译:

机械合金化和火花等离子体烧结制备的铝-高熵合金复合材料的组织和性能

通过机械合金化和火花等离子体烧结(SPS)制备了高质量的铝-CuZrNiAlTiW高熵合金(HEA)复合材料。研究了这些复合材料的微观结构,力学性能和耐腐蚀性。研磨后的HEA粉末由单一的体心立方(BCC)固溶体相组成。除了Al和BCC相以外,由于基体和HEA增强材料之间的Al浓度梯度大,在烧结复合材料中原位形成了富NiAl的B2和WAl 12相。与SPS-ed Al块相比,Al-HEA复合材料显示出更高的显微硬度和强度,这归因于BCC相的分散强化和B2和WAl 12的析出强化。相位,以及严重的晶格畸变。HEA(Al10)含量为10%(体积)的复合材料中的核-壳微观结构有助于其良好的压缩性能,高屈服强度和良好的可塑性。由于BCC颗粒的尺寸和分布均匀,Al20复合材料具有544 MPa的高断裂强度。另外,W和Ni可以改善保护层的稳定性,从而增强Al-HEA复合材料在海水中的耐点蚀性。Al10复合材料具有相对正的腐蚀电位和低腐蚀速率,显示出良好的一般耐腐蚀性。

更新日期:2020-06-25
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