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Facile synthesis of novel and highly efficient CoNi2S4-Ni(OH)2 nanosheet arrays as pseudocapacitive-type electrode material for high-performance electrochemical supercapacitors
Journal of Energy Storage ( IF 9.4 ) Pub Date : 2020-06-25 , DOI: 10.1016/j.est.2020.101623
Anil Kumar Yedluri , Dasha Kumar Kulurumotlakatla , Sambasivam Sangaraju , Ihab M. Obaidat , Hee-Je Kim

In this academic research, highly efficient and novel material of CoNi2S4@Ni(OH)2 nanosheet arrays (NSAs) carried on Ni foam was experimented using a simplistic and novel hydrothermal technique. Based on the morphology's and other physical investigations of the as-developed composite was analyzed, which results suggest that the Ni(OH)2 nanoparticles have been effectively anchored into the binary CoNi2S4 nanoflake array (NFAs) surface. The composite of CoNi2S4-Ni(OH)2 NSAs nanoarchitecture contributes superior surface area with huge number of active sites to boost electrochemical reactions and excellent conveyance between electrons and ions, as we compared to CoNi2S4 NFAs. Meanwhile, taking consider to electrochemical studies, the composite CoNi2S4-Ni(OH)2 NSAs exhibited extraordinary Faradaic redox progress, which was different from the metal-oxide based electrodes profiles. Due to the fact of better electrical conductivity with finest pseudocapacitance material of Ni(OH)2 in combination with the quick transportation of ion/electron pathways of CoNi2S4 nanoflake arrays, the procured unique construction of CoNi2S4@Ni(OH)2 NSAs exhibits an boosted up pseudocapacitive capabilities of about 251.3 mA h g−1 at a current density of 1 A g−1, which was almost two-fold superior than that of the pristine CoNi2S4 nanoflake arrays (NFAs) sample (134.2 mA h g−1). Interestingly, the composite CoNi2S4@Ni(OH)2 NSAs electrode delivered finest cycling stability which was 97.91% preserved after 5000 long-cycles. For that reasons, the novel composite of CoNi2S4@Ni(OH)2 NSAs electrode can be favorable energy storage sources for high capability supercapacitors (SCs) applications.



中文翻译:

新型高效合成CoNi 2 S 4 -Ni(OH)2纳米片阵列作为拟电容型高性能电化学超级电容器电极材料的合成

在这项学术研究中,使用一种简单而新颖的水热技术对CoNi 2 S 4 @Ni(OH)2纳米片阵列(NSA)上的高效新颖材料进行了实验。基于形态和其他物理研究,对已开发的复合材料进行了分析,结果表明Ni(OH)2纳米颗粒已被有效地锚固在二元CoNi 2 S 4纳米片阵列(NFA)表面。CoNi 2 S 4 -Ni(OH)2的复合物与CoNi 2 S 4 NFA相比,NSAs纳米结构具有卓越的表面积和大量的活性位点,可促进电化学反应以及电子和离子之间的出色传输。同时,考虑到电化学研究,复合CoNi 2 S 4 -Ni(OH)2 NSA表现出了非同寻常的法拉第氧化还原进展,这与基于金属氧化物的电极分布不同。由于使用了最好的拟电容材料Ni(OH)2具有更好的导电性,并结合了CoNi 2 S 4的离子/电子通道的快速传输纳米片阵列,CoNi 2 S 4 @Ni(OH)2 NSAs的独特构造获得了在1 A g -1的电流密度下具有约251.3 mA hg -1的增强的伪电容能力,这几乎是其两倍的优势比原始CoNi 2 S 4纳米片阵列(NFAs)样品(134.2 mA hg -1)高。有趣的是,复合CoNi 2 S 4 @Ni(OH)2 NSAs电极提供了最好的循环稳定性,经过5000个长循环后,其保留了97.91%的循环稳定性。因此,CoNi 2 S 4 @Ni(OH)的新型复合物2 NSA电极可以作为高性能超级电容器(SCs)应用的有利储能源。

更新日期:2020-06-25
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