Abstract We provide a solution for absolute analysis that has been an unrealized goal for decades. We performed hard modeling of a titration curve to generate a calculation formula to directly estimate the stoichiometric point directly. We show that the method error is negligible when the formation constant of a titration reaction is moderately large. Two examples are given to show how to apply the developed theory in practical quantitative analysis.

中文翻译：

---

用于绝对分析的滴定曲线的硬建模

摘要 我们为绝对分析提供了一个解决方案，该解决方案几十年来一直是未实现的目标。我们对滴定曲线进行了硬建模以生成直接估计化学计量点的计算公式。我们表明，当滴定反应的形成常数适中时，方法误差可以忽略不计。给出了两个例子来说明如何将发展的理论应用于实际的定量分析。