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Flexible fabric gas sensors based on PANI/WO 3 p−n heterojunction for high performance NH 3 detection at room temperature
Science China Materials ( IF 8.1 ) Pub Date : 2020-06-19 , DOI: 10.1007/s40843-020-1364-4
Meng He , Lili Xie , Guifang Luo , Zhanhong Li , James Wright , Zhigang Zhu

A PANI/WO3@cotton thread-based flexible sensor that is capable of detecting NH3 at room temperature is developed here. A layer of WO3 with PANI nanoparticles can be deposited by in-situ polymerization. The morphology and structure of the specimens were investigated by utilizing TEM, SEM, XRD and FTIR. The sensing performance of the PANI/WO3@cotton sensors with different WO3 molar ratios to NH3 at room temperature was examined. The results show that the optimal sensor (10 mol% WO3) has a response of 6.0 to 100 ppm NH3, which is significantly higher than that of the sensors based on pristine PANI and other composites. The PANI/WO3@cotton sensor also displays excellent selectivity, gas response, and flexibility even at room temperature. The unique fiber structure, p-n heterojunction, and the increased protonation of PANI in the composites contribute to the enhanced sensing property.



中文翻译:

基于PANI / WO 3 p-n异质结的柔性织物气体传感器,用于室温下的高性能NH 3检测

在此开发了一种能够在室温下检测NH 3的基于PANI / WO 3 @棉线的柔性传感器。可以通过原位聚合沉积具有PANI纳米颗粒的WO 3层。利用TEM,SEM,XRD和FTIR对样品的形貌和结构进行了研究。研究了室温下不同WO 3摩尔比与NH 3的PANI / WO 3棉传感器的传感性能。结果表明,最佳传感器(10 mol%WO 3)具有6.0至100 ppm NH 3的响应,明显高于基于原始PANI和其他复合材料的传感器。即使在室温下,PANI / WO 3棉传感器也显示出出色的选择性,气体响应和灵活性。复合材料中独特的纤维结构,pn异质结和PANI的质子化增强有助于增强传感性能。

更新日期:2020-06-25
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