cis-Specific ring opening metathesis polymerisation (ROMP) of cyclic olefins using (pentafluorophenylimido)vanadium(V)-alkylidene, V(CHSiMe3)(NC6F5)[OC(CF3)3](PMe3)2,Catalysis Science & Technology

当前位置： X-MOL 学术 › Catal. Sci. Technol. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

cis-Specific ring opening metathesis polymerisation (ROMP) of cyclic olefins using (pentafluorophenylimido)vanadium(V)-alkylidene, V(CHSiMe3)(NC6F5)[OC(CF3)3](PMe3)2
Catalysis Science & Technology ( IF 5 ) Pub Date : 2020-06-23 , DOI: 10.1039/d0cy00938e
Kotohiro Nomura _{1,

2,

3,

4} , Sapanna Chaimongkolkunasin _{1,

2,

3,

4}

Affiliation

Highly cis-specific (Z selective) ring opening metathesis polymerisation of cycloheptene (CHPE) as well as norbornene has been demonstrated using (pentafluorophenylimido)vanadium(V)-alkylidene, V(CHSiMe₃)(NC₆F₅)[OC(CF₃)₃](PMe₃)₂; the molecular weight of poly(CHPE) increased with increasing polymer yield.

中文翻译：

使用（五氟苯基亚氨基）钒（V）-亚烷基，V（CHSiMe3）（NC6F5）[OC（CF3）3]（PMe3）2的环烯烃的顺式特定开环易位聚合（ROMP）

使用（五氟苯基亚氨基）钒（V）-亚烷基，V（CHSiMe ₃）（NC ₆ F ₅）[OC（CF ），已证明环庚烯（CHPE）和降冰片烯的高度顺式（Z选择性）开环易位聚合₃）₃ ]（PMe ₃）₂；聚（CHPE）的分子量随聚合物产率的增加而增加。

更新日期：2020-06-23

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南

全部期刊列表>>