Microporous and Mesoporous Materials ( IF 5.2 ) Pub Date : 2020-06-23 , DOI: 10.1016/j.micromeso.2020.110391 Ahmed M. Alloush , Mahmoud M. Abdelnaby , Kyle E. Cordova , Naef A.A. Qasem , Bassem A. Al-Maythalony , Almaz Jalilov , Youcef Mankour , Othman Charles S. Al Hamouz
A novel crosslinked microporous polymer was synthesized via a modified acid-catalyzed Friedel-Crafts polycondensation reaction. By virtue of the rigid and polarizable monomers (aniline and pyrrole), the polymer, termed KFUPM-4, was proven permanently porous (Brunauer-Emmett-Teller surface area = 650 m2 g−1) with a high CO2 capacity (33 cm3 g−1 at 760 Torr and 298 K) and selectivity (CO2:CH4 selectivity = 15:1 at 298 K). As a result of these properties, KFUPM-4 was subjected to breakthrough measurements, whereby the material's ability to selectively capture CO2 under dynamic conditions from both dry and wet mixed gas streams was clearly demonstrated.
中文翻译:
使用新型微孔有机共聚物从混合气流中选择性捕获二氧化碳
通过改性的酸催化的Friedel-Crafts缩聚反应合成了新型的交联微孔聚合物。借助于刚性和可极化的单体(苯胺和吡咯),被称为KFUPM-4的聚合物被证明是永久多孔的(Brunauer-Emmett-Teller表面积= 650 m 2 g -1),具有较高的CO 2容量(33)。 cm 3 g -1在760 Torr和298 K下)和选择性(在298 K下CO 2:CH 4选择性= 15:1)。由于这些特性,对KFUPM-4进行了突破性的测量,从而使材料具有选择性捕获CO 2的能力。 在动态条件下,干,湿混合气流均得到了清晰证明。