Journal of Solid State Chemistry ( IF 3.3 ) Pub Date : 2020-06-23 , DOI: 10.1016/j.jssc.2020.121509 Zuzanna Ryżyńska , Tomasz Klimczuk , Michał J. Winiarski
Single crystals of SrCo2Al and BaCo2Al9 were grown using a self-flux method. A LeBail analysis of the powder X-ray diffraction patterns show that both compounds crystallize in a hexagonal (P6/mmm) crystal structure with lattice parameters: a = 7.8995(1) Å, c = 3.9159(1) Å for SrCo2Al9, and a = 7.9162(2) Å, c = 3.9702(1) Å for BaCo2Al9 aluminide. The low temperature analysis of the heat capacity measurements give a Sommerfeld coefficient γ = 4.99(6) mJ mol−1 K−2 for SrCo2Al9 and almost twice larger γ = 7.94(9) mJ mol−1 K−2 for BaCo2Al9. Resistivity measurements show metallic-like behavior, with reasonably large residual resistivity ratio RRR = 6 and 10 for SrCo2Al9 and BaCo2Al9, respectively. Neither heat capacity nor resistivity measurements reveal any phase transition down to 1.8 K.
中文翻译:
M Co 2 Al 9(M = Sr,Ba)的单晶生长和物理性质
使用自通量法生长SrCo 2 Al和BaCo 2 Al 9的单晶。粉末X射线衍射图的LeBail分析表明,两种化合物均以具有晶格参数的六边形(P6 / mmm)晶体结构结晶:a = 7.8995(1)Å,c = 3.9159(1)Å SrCo 2 Al 9, 对于BaCo 2 Al 9铝化物,a = 7.9162(2)Å,c = 3.9702(1)Å 。热容量测量的低温分析得出Sommerfeld系数γ = 4.99(6)mJ mol-1 ķ -2为的SrCO 2的Al 9和几乎两倍更大的γ = 7.94(9)毫焦摩尔-1 ķ -2为BACO 2的Al 9。电阻率的测量结果表明金属样行为,具有相当大的剩余电阻率比值RRR = 6和10的SrCO 2的Al 9和BACO 2的Al 9分别。热容量和电阻率测量均未显示任何低至1.8 K的相变。