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Dissolution mechanism of sodium alginate and properties of its regenerated fiber under low temperature.
International Journal of Biological Macromolecules ( IF 8.2 ) Pub Date : 2020-06-23 , DOI: 10.1016/j.ijbiomac.2020.06.192
Weidong Zhou 1 , Hong Zhang 1 , Yue Yu 1 , Xinquan Zou 1 , Junfeng Shi 1 , Yunhe Zhao 1 , Yongming Ye 1
Affiliation  

Sodium alginate (SA) solution with high quality fraction was prepared by NaOH/urea, NaOH/thiourea/urea, NaOH/thiourea and LiOH/urea at low temperature. The results showed that we got 5.5 wt% SA solution by using 5.5 wt% LiOH/20 wt% urea. The viscosity of the solution was 62.44 Pa·s, which had declined by 64% compared to that of 5 wt% SA solution (176.12 Pa·s). The difference from the traditional low temperature dissolution principle is that the urea is mainly wrapped on the SA surface by the interaction between the OH in LiOH through the ether bond (O) and the π bond in the SA instead of the -OH in the SA. Only the crystallization peak of urea appeared in the XRD spectrum. It indicated that urea was successfully wrapped on the surface of SA to form urea-LiOH-SA inclusion complex. The 23Na NMR showed that the interaction between Na+ and other ions or molecules around it increased at low temperature. Breaking strength of regenerated CA was 2.44 cN/dtex, which rose by about 21.39% compared to that of CA fiber (2.01 cN/dtex). The “groove” on the surface of regenerated fiber is denser and the section is more loosely compared with those of CA fiber.



中文翻译:

海藻酸钠的溶解机理及其再生纤维的低温性能

低温下用NaOH /尿素,NaOH /硫脲/尿素,NaOH /硫脲和LiOH /尿素制备出高质量的藻酸钠溶液。结果表明,通过使用5.5重量%的LiOH / 20重量%的尿素,我们得到了5.5重量%的SA溶液。溶液的粘度为62.44 Pa·s,与5 wt%的SA溶液(176.12 Pa·s)相比下降了64%。从传统的低温溶解原理的不同之处在于脲由OH之间的相互作用主要是缠绕在SA表面上-在LiOH通过醚键(Ô)和SA中的π键,而不是SA中的-OH。在XRD谱图中仅出现尿素的结晶峰。这表明尿素被成功包裹在SA表面,形成尿素-LiOH-SA包合物。的23的Na NMR表明:Na之间的相互作用+和其它离子或在其周围的分子在低温下增加。再生CA的断裂强度为2.44 cN / dtex,比CA纤维(2.01 cN / dtex)的断裂强度提高了约21.39%。与CA纤维相比,再生纤维表面的“凹槽”更致密,截面更松散。

更新日期:2020-06-30
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