International Journal of Biological Macromolecules ( IF 8.2 ) Pub Date : 2020-06-23 , DOI: 10.1016/j.ijbiomac.2020.06.192 Weidong Zhou 1 , Hong Zhang 1 , Yue Yu 1 , Xinquan Zou 1 , Junfeng Shi 1 , Yunhe Zhao 1 , Yongming Ye 1
Sodium alginate (SA) solution with high quality fraction was prepared by NaOH/urea, NaOH/thiourea/urea, NaOH/thiourea and LiOH/urea at low temperature. The results showed that we got 5.5 wt% SA solution by using 5.5 wt% LiOH/20 wt% urea. The viscosity of the solution was 62.44 Pa·s, which had declined by 64% compared to that of 5 wt% SA solution (176.12 Pa·s). The difference from the traditional low temperature dissolution principle is that the urea is mainly wrapped on the SA surface by the interaction between the OH− in LiOH through the ether bond (O) and the π bond in the SA instead of the -OH in the SA. Only the crystallization peak of urea appeared in the XRD spectrum. It indicated that urea was successfully wrapped on the surface of SA to form urea-LiOH-SA inclusion complex. The 23Na NMR showed that the interaction between Na+ and other ions or molecules around it increased at low temperature. Breaking strength of regenerated CA was 2.44 cN/dtex, which rose by about 21.39% compared to that of CA fiber (2.01 cN/dtex). The “groove” on the surface of regenerated fiber is denser and the section is more loosely compared with those of CA fiber.
中文翻译:
海藻酸钠的溶解机理及其再生纤维的低温性能
低温下用NaOH /尿素,NaOH /硫脲/尿素,NaOH /硫脲和LiOH /尿素制备出高质量的藻酸钠溶液。结果表明,通过使用5.5重量%的LiOH / 20重量%的尿素,我们得到了5.5重量%的SA溶液。溶液的粘度为62.44 Pa·s,与5 wt%的SA溶液(176.12 Pa·s)相比下降了64%。从传统的低温溶解原理的不同之处在于脲由OH之间的相互作用主要是缠绕在SA表面上-在LiOH通过醚键(Ô)和SA中的π键,而不是SA中的-OH。在XRD谱图中仅出现尿素的结晶峰。这表明尿素被成功包裹在SA表面,形成尿素-LiOH-SA包合物。的23的Na NMR表明:Na之间的相互作用+和其它离子或在其周围的分子在低温下增加。再生CA的断裂强度为2.44 cN / dtex,比CA纤维(2.01 cN / dtex)的断裂强度提高了约21.39%。与CA纤维相比,再生纤维表面的“凹槽”更致密,截面更松散。