Resonant injection and resulting charge storage were examined in a large-area carbon/tetraphenylporphyrin(TPP)/LiF/carbon junction, where the LiF layer provides mobile ions in acetonitrile (ACN) vapor. Resonant electron transfer into TPP molecules occurs at <+1V in the presence of mobile ions, enabled by ionic screening of the carbon electrode. Injection of holes, i.e. formation of TPP radi-cal cation, inside the junction was monitored by in-situ photocurrent measurements. Following the injection, despite the lack of a redox counter-reaction or conventional electrolyte, persistent faradaic current peaks dominate the IV cycle of the junction (±2V) in ACN vapor, enhancing the reversible charge storage by a factor of 78 compared to that in vacuum.

中文翻译：

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碳基分子结中的离子辅助共振注入和电荷存储

在大面积的碳/四苯基卟啉 (TPP)/LiF/碳结中检查共振注入和由此产生的电荷存储，其中 LiF 层提供乙腈 (ACN) 蒸汽中的移动离子。在移动离子存在的情况下，共振电子转移到 TPP 分子时发生在 <+1V，这通过碳电极的离子屏蔽实现。通过原位光电流测量监测结内的空穴注入，即TPP自由基阳离子的形成。注入后，尽管缺乏氧化还原反反应或常规电解质，但持续的法拉第电流峰值主导着 ACN 蒸气中结 (±2V) 的 IV 循环，与在 ACN 中的可逆电荷存储相比，可逆电荷存储提高了 78 倍。真空。