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Synthesis of new fluorescent molecules having an aggregation-induced emission property derived from 4-fluoroisoxazoles.
Beilstein Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2020-06-22 , DOI: 10.3762/bjoc.16.117
Kazuyuki Sato 1 , Akira Kawasaki 1 , Yukiko Karuo 1 , Atsushi Tarui 1 , Kentaro Kawai 1 , Masaaki Omote 1
Affiliation  

Fluorescent molecules based on a fluorinated isoxazole scaffold were synthesized and investigated for their photochemical properties. The introduction of a fluorine substituent into 3,5-diarylisoxazoles led to an increase of fluorescence intensity and exhibited a redshift in the emission intensity. α-Fluorinated boron ketoiminates (F-BKIs) were also synthesized via a ring-opening reaction of 4-fluoroisoxazoles and exhibited highly fluorescent luminescence and aggregation-induced emission (AIE), showing promise as a new fluorophore.

中文翻译:

具有4-氟异恶唑衍生的具有聚集诱导发射特性的新型荧光分子的合成。

合成了基于氟化异恶唑支架的荧光分子,并对其光化学性质进行了研究。将氟取代基引入3,5-二芳基异恶唑中导致荧光强度增加并且显示出发射强度的红移。还通过4-氟异恶唑的开环反应合成了α-氟代酮化金属(F-BKIs),并显示出高荧光发光和聚集诱导发射(AIE),显示出有望作为一种新的荧光团。
更新日期:2020-06-22
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