Abstract Fluorescent brighteners mediated, thiol-ene polymerizations retain the robustness of step-growth mechanism meanwhile introducing new features: biocompatible wavelengths of visible light and aqueous reaction conditions. The proposed visible-light thiol-ene polymerization of trithiol − triene monomer is shown to be an innovative, facile, and highly efficient route that constructs a versatile platform for synthesizing high-performance coatings and multifuctional intelligent nanoparticles, respectively performed in a bulk form and emulsion form. In particular, the achievement of the concept of natural-sunlight-triggered thiol-ene polymerization is extremely valuable for coating synthesis as the method is green and friendly to environment in a sustainable manner. Besides, the resulting poly(thioester) latexes are capable of being applicable as multi-stimuli-responsive nanocarriers sensitive to UV, pH and redox.

中文翻译：

---

硫醇-丙烯酸酯聚合中的荧光增白剂：阳光固化涂层和 LED 辅助多功能智能纳米粒子合成

摘要 荧光增白剂介导的硫醇-烯聚合保留了逐步增长机制的稳健性，同时引入了新特性：可见光的生物相容性波长和水性反应条件。三硫醇-三烯单体的可见光硫醇-烯聚合被证明是一种创新、简便且高效的途径，构建了一个多功能平台，用于合成高性能涂层和多功能智能纳米粒子，分别以本体形式和乳液形式。特别是，自然阳光触发硫醇烯聚合概念的实现对于涂料合成非常有价值，因为该方法以可持续的方式绿色且对环境友好。除了，