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A mini review of cobalt-based nanocatalyst in Fischer-Tropsch synthesis
Applied Catalysis A: General ( IF 5.5 ) Pub Date : 2020-06-19 , DOI: 10.1016/j.apcata.2020.117701
Zhiyuan Qi , Luning Chen , Shuchen Zhang , Ji Su , Gabor A. Somorjai

Fischer-Tropsch (F-T) synthesis, converting syngas to hydrocarbons, provides a green alternative for fuel production. Cobalt is one of the most intensively studied F-T catalysts due to its great activity, high stability, and relatively low cost. In this mini review, we summarized some recent advancements in the development of cobalt-based F-T catalysts focusing on the effects of particle size, surface oxidation states, crystallography, and bimetallic particles, with emphasis on the research from our group. Furthermore, non-steady state conditions were investigated to access the initial kinetics using chemical transient kinetics (CTK) experiments, which could bring more insights into the reaction mechanism and catalyst design.



中文翻译:

费-托合成中钴基纳米催化剂的简要回顾

费托合成(FT)将合成气转化为碳氢化合物,为燃料生产提供了绿色替代方案。钴由于其高活性,高稳定性和相对较低的成本而成为研究最深入的FT催化剂之一。在这个小型综述中,我们总结了钴基FT催化剂开发的一些最新进展,重点是粒度,表面氧化态,晶体学和双金属颗粒的影响,重点是我们小组的研究。此外,使用化学瞬变动力学(CTK)实验研究了非稳态条件以获取初始动力学,这可以为反应机理和催化剂设计带来更多的见识。

更新日期:2020-07-06
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