Compensatory (or compensation) copolymerization of alkyl (meth)acrylates (AMA) with boiling vinyl butyl ether (VBE), initiated by the system of triethylborane (TEB)–oxygen, has been studied. The obtained data indicate a partial formation of copolymer macromolecules with close to an alternating structure, according to the reversible inhibition mechanism, along with a copolymer formation on the scheme of conventional bimolecular termination. Specific features of used acrylic monomers have been revealed. Copolymers of methyl methacrylate (MMA) and VBE were applied as macroinitiators for block-copolymer syntheses when adding new portions of butyl acrylate (BA).

研究了由三乙基硼烷（TEB）-氧气体系引发的（甲基）丙烯酸烷基酯（AMA）与沸腾的乙烯基丁基醚（VBE）的补偿（或补偿）共聚。所得数据表明，根据可逆抑制机理，部分具有接近交替结构的共聚物大分子的部分形成，以及根据常规双分子终止方案的共聚物形成。已经揭示了所用丙烯酸单体的具体特征。当添加新的丙烯酸丁酯（BA）部分时，将甲基丙烯酸甲酯（MMA）和VBE的共聚物用作嵌段共聚物合成的大分子引发剂。