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Recent advances in synthesis of organometallic complexes of indium
Reviews in Inorganic Chemistry ( IF 4.1 ) Pub Date : 2020-09-25 , DOI: 10.1515/revic-2020-0005
Hira Anwar 1, 2 , Rosenani A. Haque 3 , Rahman Shah Zaib Saleem 4 , Muhammad Adnan Iqbal 1, 5
Affiliation  

Abstract The indium complexes are being used in many applications like catalysis, optoelectronics, sensors, solar cells, biochemistry, medicine, infrared (IR) mirrors and thin-film transistors (TFTs). In organometallic complexes of indium, it forms different types of complexes with single, double, triple and tetra linkages by coordinating with numerous elements like C, N, O and S and also with some other elements like Se and Ru. So, the present study comprises all the possible ways to synthesize the indium complexes by reacting with different organic ligands; most of them are N-heterocyclic carbenes, amines, amides and phenols. The commonly used solvents for these syntheses are tetrahydrofuran, dichloromethane, toluene, benzene, dimethyl sulfoxide (DMSO) and water. According to the nature of the ligands, indium complexes were reported at different temperatures and stirring time. Because of their unique characteristics, the organometallic chemistry of group 13 metal indium complexes remains a subject of continuing interest in synthetic chemistry as well as material science.

中文翻译:

铟有机金属配合物的合成新进展

摘要 铟配合物被广泛应用于催化、光电、传感器、太阳能电池、生物化学、医学、红外 (IR) 反射镜和薄膜晶体管 (TFT) 等领域。在铟的有机金属配合物中,它通过与多种元素如 C、N、O 和 S 以及其他一些元素如 Se 和 Ru 配位形成具有单键、双键、三键和四键的不同类型的配合物。因此,本研究包括通过与不同的有机配体反应来合成铟配合物的所有可能方法;其中大部分是N-杂环卡宾、胺、酰胺和酚。这些合成中常用的溶剂是四氢呋喃、二氯甲烷、甲苯、苯、二甲基亚砜 (DMSO) 和水。根据配体的性质,报道了不同温度和搅拌时间下的铟配合物。由于其独特的特性,第 13 族金属铟配合物的有机金属化学仍然是合成化学和材料科学中持续关注的主题。
更新日期:2020-09-25
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