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Structure-Activity Relationships of Voltaglue Organic Blends.
Macromolecular Rapid Communications ( IF 4.6 ) Pub Date : 2020-06-16 , DOI: 10.1002/marc.202000188
Nigel C S Tan 1 , Animesh Ghosh 1 , Terry W J Steele 1
Affiliation  

Voltage‐activated, one‐pot adhesives are an emerging platform with many potential advantages, but require multicomponent grafting of electrochemical donors and acceptors for operation in organic environments. This formulation strategy reduces throughput efficiency, organic solubility, and requires additional purification of the grafted dendrimers. A more advanced strategy is proposed for setting up the donor–acceptor conductive network by exploiting a flexible blending design, providing faster throughput of structure–activity analyses with less synthetic investment. The blend method investigates the ampere‐dependent storage modulus and gelation time as a function of both donor and acceptor concentration. This blend strategy allows a rapid evaluation of donor–acceptor parameters involved in voltage‐activated adhesive formulations.

中文翻译:

Voltaglue有机共混物的结构活性关系。

电压激活的单锅粘合剂是一个新兴平台,具有许多潜在的优势,但需要在有机环境中进行操作的电化学供体和受体的多组分接枝。这种配制策略降低了生产效率,有机溶解度,并且需要对接枝的树枝状大分子进行额外的纯化。提出了一种更高级的策略,通过利用灵活的混合设计来建立供体-受体导电网络,从而以更少的合成投资提供更快的结构活性分析通量。混合法研究了依赖于安培的储能模量和胶凝时间随供体和受体浓度的变化。这种混合策略可以快速评估电压活化胶粘剂配方中的供体-受体参数。
更新日期:2020-06-16
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