Zr⁴⁺ metal‐organic frameworks (Zr‐MOFs) , known for excellent stability and functionality, meet the synthetic challenge in tuning the strength of a Zr−O_carboxylate linkage. This work explores the unusual coordination dynamics of a family of fluorinated Zr‐MOFs. The low‐connecting kinetic Zr‐MOFs possess dynamic behavior, thus opening a post‐synthetic pathway to sequential reassembly/disassembly. The factors, such as ligand geometry, etc., have been studied. Their stability, hydrophobicity and gas adsorption/separation properties are explored. More information can be found in the Full Paper by Z.‐W. Wei, G. Maurin, C.‐Y. Su, et al. on page 8254.

中文翻译：

---

封面人物：氟化Zr-MOF的动态配位化学：从头合成以外的合成控制和重组装/拆卸，以调节结构和性能（Eur。J. 37/2020）

Zr ⁴⁺金属有机骨架（Zr-MOF）以出色的稳定性和功能性着称，在调节Zr-O_羧酸酯键的强度方面遇到了合成难题。这项工作探索了氟化Zr-MOF系列的异常配位动力学。低连接的动力学Zr-MOF具有动力学行为，因此为顺序重新组装/拆卸打开了合成后的途径。已经研究了诸如配体几何形状等因素。探索了它们的稳定性，疏水性和气体吸附/分离特性。可以在Z.‐W的《全文》中找到更多信息。Wei，G.Maurin，C.Y. Su等。在8254页。