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Augmenting the nickel-cobalt layered double hydroxide performance: Virtue of doping
Journal of Energy Storage ( IF 9.4 ) Pub Date : 2020-06-16 , DOI: 10.1016/j.est.2020.101604
Alisha Nanwani , Kavita A. Deshmukh , Chandrasekar M Subramaniyam , Abhay D. Deshmukh

Doping is the most effective strategy to improve the electrochemical performance of supercapacitors. Herein, we report the doping effect of Magnesium on structural instability of Ni-Co LDHs as the supercapacitor electrode material. The morphology of different compositions of magnesium are studied. The derived material with the Ni:Mg ratio of 1:1 displayed an excellent specific capacity of 624 Cg−1 at current density of 10 Ag−1. Moreover, the specific capacity remained at 80% after 3000 cycles which suggest excellent cycle stability. An asymmetrc device was fabricated with N/M2 as positive electrode and activated carbon cloth as negative electrode, which displayed a specific capacitance of 200 Fg−1 at 0.25 Ag−1 with the energy density of 28 Whkg−1. The device showed the capacitance retention of about 99% after 1000 cycles at 1 Ag−1. Therefore, improved structural integrity, makes this material a suitable candidate for supercapacitors.



中文翻译:

增强镍钴层状双氢氧化物的性能:掺杂的美德

掺杂是提高超级电容器电化学性能的最有效策略。在此,我们报道了镁对作为超级电容器电极材料的Ni-Co LDHs的结构不稳定性的掺杂作用。研究了镁不同组成的形态。Ni∶Mg比为1∶1的衍生材料在10 Ag -1的电流密度下显示出624 Cg -1的优异比电容。此外,在3000次循环后,比容量保持在80%,这表明优异的循环稳定性。一个asymmetrc装置用N / M制成2作为正极和活性炭布作为负电极,其显示200 FG的特定电容-1为0.25的Ag -1能量密度为28 Whkg -1。该器件在1 Ag -1下经过1000次循环后显示出约99%的电容保持率。因此,改善的结构完整性使该材料成为超级电容器的合适候选材料。

更新日期:2020-06-16
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