Journal of Energy Storage ( IF 9.4 ) Pub Date : 2020-06-17 , DOI: 10.1016/j.est.2020.101609 Kaiyuan Shi , Jiangwen Liu , Ri Chen
Lithium-ion Capacitor is emerging as a promising strategy that integrated high energy of Lithium-ion batteries with high power of supercapacitors. However, conventional activated carbon presents great challenges as supercapacitive electrodes. In this work, porous nano-carbon onion rings (NCOR) with N-doping were synthesized via the pyrolysis of nanoarchitecture precursor, which yielded a surface area of 1769.76 m2 g − 1. The NCOR electrode showed a capacity of 68.78 mAh g − 1 with a stable capacity retention of 83.12% after 1000 cycles in a voltage window of 2.5–4.2 V vs. Li/Li+. The impedance tests measured at different potentials shed some light on the mechanism of charge storage. We demonstrated the promise of NCOR for energy storage in Lithium-ion capacitors.
中文翻译:
氮掺杂纳米碳洋葱圈,用于在锂离子电容器中存储能量
锂离子电容器正在成为一种有前途的战略,它将锂离子电池的高能量与高功率的超级电容器集成在一起。然而,传统的活性炭作为超级电容电极提出了巨大的挑战。在这项工作中,多孔纳米碳洋葱圈(NCOR)与N-掺杂合成通过纳米架构前体的热解,其产生的1769.76米表面积2 克 - 1。所述NCOR电极显示出68.78毫安的容量克 - 1在2.5-4.2 V相对于的电压窗口1000次循环后的83.12%的稳定的容量保持率。锂/锂+。在不同电位下测得的阻抗测试为电荷存储的机理提供了一些启示。我们展示了NCOR在锂离子电容器中储能的前景。