Catalytic reductive deoxygenation of esters to ethers driven by hydrosilane activation through non-covalent interactions with a fluorinated borate salt,Catalysis Science & Technology

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Catalytic reductive deoxygenation of esters to ethers driven by hydrosilane activation through non-covalent interactions with a fluorinated borate salt
Catalysis Science & Technology ( IF 5 ) Pub Date : 2020-06-15 , DOI: 10.1039/d0cy00775g
Vincent Rysak _{1,

2,

3,

4,

5} , Ruchi Dixit _{6,

7,

8,

9,

10} , Xavier Trivelli _{1,

2,

3,

4,

11} , Nicolas Merle _{1,

2,

3,

4,

5} , Francine Agbossou-Niedercorn _{1,

2,

3,

4,

5} , Kumar Vanka _{6,

7,

8,

9} , Christophe Michon _{1,

2,

3,

4,

5}

Affiliation

We report the catalytic and transition metal-free reductive deoxygenation of esters to ethers through the use of a hydrosilane and a fluorinated borate BArF salt as a catalyst. Experimental and theoretical studies support the role of noncovalent interactions between the fluorinated catalyst, the hydrosilane and the ester substrate in the reaction mechanism.

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