Abstract

The role of hydrated electrons in sonochemiluminescence (SCL) arising from the single- and multibubble sonolysis of aqueous solutions of \({\text{Ru(bpy)}}_{{\text{3}}}^{{{\text{2 + }}}}\) and \({\text{Ru(bpy)}}_{{\text{3}}}^{{{\text{3 + }}}}\) is revealed. Possible chemiluminescent reactions between ruthenium ions and the products of water sonolysis are considered. A conclusion is drawn concerning the previously unknown formation of e_aq upon the single-bubble sonolysis of water and the absence of this product upon multibubble sonolysis.

中文翻译：

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$$溶液的超声分析中的$$ {\ mathbf {Ru（bpy）}} _ {{\ mathbf {3}}} ^ {{{\ mathbf {2 +}}}}} $$的电子激发发光{\ mathbf {Ru（bpy）}} _ {{\ mathbf {2 +}}}} $$和$$ {\ mathbf {Ru（bpy）}} __ { {\ mathbf {3}}} ^ {{{\ mathbf {3 +}}}}} $$

摘要

\（{\ text {Ru（bpy）}} _ {{\ text {3}} ^^ {{{\ text}水溶液的单泡和多泡声解法产生的水合电子在超声发光（SCL）中的作用{2 +}}}} \）和\（{\ text {Ru（bpy）}} _ {{\ text {3}}} ^ {{{\ text {3 +}}}} \\）。考虑了钌离子与水声分解产物之间可能的化学发光反应。甲得出结论关于先前未知的地层的Ë_水溶液时的水的单泡超声波分解并且在multibubble超声波分解不存在此产物。