Fluorinated derivatization agents allow for the identification and quantification of emerging pollutants with high sensitivity, yet details of their potential applications using electron ionization are lacking. The fluorine atom itself does not effectively participate in electron ionization. Furthermore, limited information exists regarding the effect of fluorine during electron ionization‐induced fragmentation. To fill this gap, this report presents the fragmentation pathways of the fluorinated derivatives of ten bisphenol analogues as exemplary emerging pollutants.

中文翻译：

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电子电离引起双酚氟化衍生物的断裂。

氟化衍生剂可以高灵敏度地鉴定和定量新兴污染物，但缺少使用电子电离技术潜在应用的详细信息。氟原子本身不能有效地参与电子电离。此外，关于氟在电子电离诱导的碎裂过程中的作用的信息有限。为了填补这一空白，本报告介绍了十种双酚类似物的氟化衍生物作为新兴污染物的裂解途径。