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Synthesis of Glux based polymers for removal of benzene derivatives and pesticides from water
Polymers for Advanced Technologies ( IF 3.4 ) Pub Date : 2020-06-11 , DOI: 10.1002/pat.4953
Taha Chabbah 1, 2 , Houyem Abderrazak 3 , Patrice Saint Martin 4 , Hervé Casabianca 4 , Hans R. Kricheldorf 5 , Saber Chatti 1
Affiliation  

In this study, biomass‐derived Glux was used as a monomer in the polymerization of a novel semi‐aromatic polyethersulfone and polyester. The characterization of the synthesized polymers was carried out by means of MALDI‐TOF and NMR spectroscopy, differential scanning calorimetry, and thermogravimetric analysis. These two polymers were tested as sorbent phases of two families of pollutants (benzene derivatives and pesticides) in water. The analysis of the target hydrophilic pollutants was successfully achieved using high performance liquid chromatography meanwhile gas chromatography was applied for the detection of the hydrophobic pollutants. The adsorption data demonstrate that the novel polyethersulfone based on Glux can effectively remove the studied organic pollutants (polar and non polar, 90% to 100%) at environmental concentration (tested concentration: 1 mg L−1) simultaneously when present in mixtures.

中文翻译:

用于从水中去除苯衍生物和农药的Glux基聚合物的合成

在这项研究中,生物质衍生的Glux被用作新型半芳族聚醚砜和聚酯聚合的单体。合成的聚合物的表征通过MALDI-TOF和NMR光谱,差示扫描量热法和热重分析进行。测试了这两种聚合物作为水中两类污染物(苯衍生物和农药)的吸附相。使用高效液相色谱法成功地完成了目标亲水性污染物的分析,同时气相色谱法用于疏水性污染物的检测。吸附数据表明,基于Glux的新型聚醚砜可以有效去除研究的有机污染物(极性和非极性,-1)同时存在于混合物中。
更新日期:2020-06-11
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