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Synthesis of New Chiral Crown Ethers Containing Phosphine or Secondary Phosphine Oxide Units
Synthesis ( IF 2.6 ) Pub Date : 2020-06-10 , DOI: 10.1055/s-0040-1707854
Péter Huszthy 1 , Hajnalka Szabó-Szentjóbi 1 , István Majoros 1 , Anna Márton 1 , Ibolya Leveles 2, 3 , Beáta G. Vértessy 2, 3 , Miklós Dékány 4 , Tünde Tóth 1, 5
Affiliation  


Abstract

The transition-metal complexes of phosphine and secondary phosphine oxide compounds can be used in various catalytic reactions. In this paper, the synthesis and characterization of eight new crown ethers containing trivalent phosphorus in their macroring are reported. These macrocycles are promising candidates as ligands for catalytic reactions.



中文翻译:

含膦或仲膦氧化物单元的新型手性冠醚的合成


摘要

膦和仲膦氧化物化合物的过渡金属络合物可用于各种催化反应中。本文报道了八种在其大环中含有三价磷的新冠醚的合成与表征。这些大环化合物有望作为催化反应的配体。

更新日期:2020-06-10
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