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One-step synthesis of few-layered-graphene/alumina powders for strong and tough composites with high electrical conductivity
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2020-06-10 , DOI: 10.1016/j.jeurceramsoc.2020.06.029
Alicia Weibel , Andréas Flaureau , Adeline Pham , Geoffroy Chevallier , Jérôme Esvan , Claude Estournès , Christophe Laurent

The chemical vapor deposition of carbon onto a commercial α-Al2O3 powder bed produces a pristine film of few-layered-graphene (FLG) uniformly covering the α-Al2O3 grains. This obviates both the manipulation of nanocarbons, lengthy mixing steps and the risk of damaging any pre-existing graphene platelets. The powders are consolidated to 99 % by SPS, producing samples where a FLG film is located along the grain boundaries of the submicron α-Al2O3. Compared to the pure α-Al2O3, the composites are moderately stronger and similarly tough and hard due to crack-deflection and crack-bridging and they are electrically conducting with a percolation threshold below 0.74 vol.% of carbon. The high conductivity values reflect the high quality of the thin FLG film and its continuous nature over very long distances. The samples are characterized by Raman spectroscopy, X-ray photoelectron spectroscopy, scanning and transmission electron microscopy.



中文翻译:

一步法合成几层石墨烯/氧化铝粉末,用于具有高电导率的强韧复合材料

碳的化学汽相沉积到商业的α-Al 2 ö 3粉末床产生较少层状石墨烯(FLG)均匀地覆盖所述α-Al的原始膜2 ö 3个晶粒。这样既避免了纳米碳的操作,冗长的混合步骤,又避免了损坏任何先前存在的石墨烯血小板的风险。粉末是采用SPS合并,以99%,产生其中FLG膜沿着所述亚微米的α-Al的晶界位于样品2 ö 3。相比于纯的α-Al 2 ö 3,由于裂纹挠曲和裂纹桥接,该复合材料具有中等强度,并且类似地坚韧,并且它们的导电阈值低于碳的0.74%(体积)。高电导率值反映了FLG薄膜的高质量及其在很长距离内的连续性。通过拉曼光谱,X射线光电子光谱,扫描和透射电子显微镜对样品进行表征。

更新日期:2020-06-10
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