A mesoporous hypercrosslinked polymer (HCP), derived from a Friedel-Crafts alkylation reaction of 1,4-bis(chloromethyl)benzene and a precursor contained heterocyclic ionic liquids, was synthesized, having a high specific surface area with abundant mesopore and specific porosity. In order to reduce 4-nitrophenol (4-NP) to 4-aminophenol (4-AP), a new bismuth nanoparticle/HCP composite (Bi/HCP) as a catalyst was prepared, where the HCP was used as a catalyst carrier. Herein, the HCP was firstly impregnated into a BiCl₃ solution to adsorb the Bi³⁺ ions. After that, these Bi³⁺ ions adsorbed were then reduced in situ using KBH₄, affording the ultimate Bi/HCP composite. In such Bi/HCPs, Bi nanoparticles with a small diameter of 1–3 nm were evenly dispersed. In this work, the Bi/HCPs exhibit an excellent catalytic performance toward the reduction of 4-NP with a low loading, the reaction rate constant k is calculated to be 2.2 min⁻¹, and the catalytic activity did not decrease even after 8 reaction cycles.

合成了具有1,4-双（氯甲基）苯与含有杂环离子液体的前体的弗瑞德-克来福特（Friedel-Crafts）烷基化反应的介孔超交联聚合物（HCP），它具有高的比表面积，丰富的介孔和比孔率。为了将4-硝基苯酚（4-NP）还原为4-氨基苯酚（4-AP），制备了新型的铋纳米粒子/ HCP复合材料（Bi / HCP）作为催化剂，其中HCP用作催化剂载体。在此，首先将HCP浸渍在BiCl ₃溶液中以吸收Bi ³⁺离子。之后，然后使用KBH ₄原位还原这些吸附的Bi ³⁺离子，提供了最终的Bi / HCP复合材料。在此类Bi / HCP中，直径为1-3 nm的Bi纳米颗粒均匀分散。在这项工作中，Bi / HCP在低负荷下表现出优异的催化还原4-NP的性能，反应速率常数k计算为2.2 min ^-1，即使经过8次反应，催化活性也没有降低周期。