Solid Brønsted acid catalysts, an important class of heterogeneous catalyst, are emerging as an ideal alternative to conventional liquid mineral acids in promoting diverse proton-catalyzed organic transformations in respect of green and sustainable chemistry. In particular, benefitting from the astonishing structural diversity, exceptional porosity as well as high modularity and tunability, Brønsted acidic metal-organic frameworks (BA-MOFs) have been extensively recognized as prominent candidates, which distinguished them from traditional solid Brønsted acids. In this paper, we summarize the recent advances of BA-MOF materials, including the design and synthesis, and their catalytic behavior in various organic transformations. The insights into the challenges and outlook on the future research direction of the field are also presented.

固态布朗斯台德酸催化剂是一类重要的非均相催化剂，在促进绿色和可持续化学方面促进质子催化的各种有机转化方面，已成为传统液态无机酸的理想替代品。尤其是得益于惊人的结构多样性，出色的孔隙率以及高模块化和可调性，布朗斯台德酸性金属-有机骨架（BA-MOF）被公认为是杰出的候选者，从而使它们与传统的固态布朗斯台德酸区别开来。在本文中，我们总结了BA-MOF材料的最新进展，包括设计和合成及其在各种有机转化中的催化行为。还介绍了该领域的挑战和对未来研究方向的见解。