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Ethanol conversion to selective high-value hydrocarbons over Ni/HZSM-5 zeolite catalyst
Catalysis Communications ( IF 3.7 ) Pub Date : 2020-06-09 , DOI: 10.1016/j.catcom.2020.106067
Chun-Yen Liu , Kim Struwe , Cheng-Hung Lee , Haw-Yeu Chuang , Jörg Sauer , Joseph Che-Chin Yu , Van-Huy Nguyen , Chao-Wei Huang , Jeffrey C.S. Wu

Bio-ethanol is a renewable fuel and can be converted to high-values chemicals. This study showed that more aromatics and gas products could be obtained at a low weight hourly space velocity (WHSV) than that at high WHSV using HZSM-5 and Ni/HZSM-5 catalysts. A low WHSV offered an increased tendency to build up aromatics and paraffins. Real bio-ethanol broth was tested and gave the similar result as pure ethanol solution. That catalysts could retain full catalytic activity after 168 h in reaction provides evidence for their long stability. This study advantageously demonstrates a promising approach to generate high-value products from bio-ethanol.



中文翻译:

Ni / HZSM-5沸石催化剂将乙醇转化为选择性高价值烃

生物乙醇是一种可再生燃料,可以转化为高价值化学品。这项研究表明,使用HZSM-5和Ni / HZSM-5催化剂,在低重量时空速(WHSV)下可以获得比在高WHSV下更多的芳烃和气体产物。低的WHSV提供了增加形成芳族化合物和石蜡的趋势。测试了真实的生物乙醇肉汤,其结果与纯乙醇溶液相似。催化剂在反应168小时后可以保留全部催化活性,为它们的长期稳定性提供了证据。这项研究有利地证明了从生物乙醇生产高价值产品的有前途的方法。

更新日期:2020-06-09
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