A di-urethane cross-linked poly(oxyethylene)/silica hybrid matrix [di-urethanesil, d-Ut(600)], synthesized by the sol-gel process, was doped with lithium triflate (LiCF₃SO₃) and the 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) ionic liquid. The as-produced xerogel film is amorphous, transparent, flexible, homogeneous, hydrophilic, and has low nanoscale surface roughness. It exhibits an ionic conductivity of 3.64 × 10^–6 and 5.00 × 10^–4 S cm^–1 at 21 and 100°C, respectively. This material was successfully tested as electrolyte in an electrochromic device (ECD) with the glass/ITO/a-WO₃/d-Ut(600)₁₀LiCF₃SO₃[Bmim]Cl/c-NiO/ITO/glass configuration, where a-WO₃ and c-NiO stand for amorphous tungsten oxide and crystalline nickel oxide, respectively. The device demonstrated attractive electro-optical performance: fast response times (1–2 s for coloring and 50 s for bleaching), good optical memory [loss of transmittance (T) of only 41% after 3 months, at 555 nm], four mode modulation [bright mode (+3.0 V, T = 77% at 555 nm), semi-bright mode (−1.0 V, T = 60% at 555 nm), dark mode (−1.5 V, T = 38 % at 555 nm), and very dark mode (−2.0 V, T = 11% and −2.5 V, T = 7% at 555 nm)], excellent cycling stability denoting improvement with time, and high coloration efficiency [CE_in = −6727 cm² C^–1 (32th cycle) and CE_out = +2794 cm² C^–1 (480th cycle), at 555 nm].

通过溶胶-凝胶法合成的二氨基甲酸酯交联的聚（氧乙烯）/二氧化硅杂化基质[di-urethanesil，d-Ut（600）]掺杂有三氟甲磺酸锂（LiCF ₃ SO ₃）和1丁基-3-甲基咪唑氯化物（[Bmim] Cl）离子液体。所生产的干凝胶膜是无定形的，透明的，柔性的，均匀的，亲水的，并且具有低的纳米级表面粗糙度。在21°C和100°C下，其离子电导率分别为3.64×10 ^–6和5.00×10 ^–4 S cm ^–1。该材料已通过玻璃/ ITO / a-WO ₃ / d-Ut（600）₁₀ LiCF ₃ SO ₃在电致变色器件（ECD）中作为电解质成功测试[Bmim] Cl / c-NiO / ITO /玻璃配置，其中a-WO ₃和c-NiO分别表示无定形氧化钨和结晶氧化镍。该设备展示出诱人的电光性能：响应时间快（着色时间为1-2秒，漂白为50秒），良好的光学记忆力（在555 nm波长下三个月后的透射率（T）仅为41％），四个模式调制[亮模式（+3.0 V，555 nm时T = 77％），半亮模式（−1.0 V，T = 555 nm时60％），暗模式（−1.5 V，T = 555时38％ nm）和非常暗的模式（在555 nm时为-2.0 V，T = 11％和-2.5 V，T = 7％）]，优异的循环稳定性表示随时间的推移而改善，并且着色效率高[CE_在= −6727 cm ² C ^–1（第32周期）和CE_出= +2794 cm ² C ^–1（第480个循环），在555 nm下]。