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Photoinduced direct hydration of dipyridylacetylenes in acidic aqueous solution.
Chemical Communications ( IF 4.9 ) Pub Date : 2020-06-05 , DOI: 10.1039/d0cc01351j
Ya Li 1 , Zimu Su , Haijun Hao , Junpeng Zhuang
Affiliation  

Photoinduced direct hydration of dipyridylacetylenes (DPAs) in acidic aqueous solution was achieved upon UV irradiation at room temperature. This is a catalyst-free reaction with moderate-to-good yields, and asymmetric dipyridylacetylenes afford the corresponding Markovnikov addition products.

中文翻译:

二吡啶基乙炔在酸性水溶液中的光诱导直接水合。

在室温下通过紫外线照射,可实现在酸性水溶液中二吡啶基乙炔(DPA)的光诱导直接水合。这是无催化剂的反应,产率中等至良好,不对称的二吡啶基乙炔可提供相应的马尔可夫尼科夫加成产物。
更新日期:2020-07-09
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