Synthesis of (+)‐Epoxydon, (–)‐Phyllostine, (–)‐RKTS 33, and (–)‐Parasitenone Featuring Selective Sulfonylation and Oxirane Ring Closure of Aldol Cyclization Products,European Journal of Organic Chemistry

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Synthesis of (+)‐Epoxydon, (–)‐Phyllostine, (–)‐RKTS 33, and (–)‐Parasitenone Featuring Selective Sulfonylation and Oxirane Ring Closure of Aldol Cyclization Products
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-06-05 , DOI: 10.1002/ejoc.202000486
Feng Shui ₁ , Junhao Jia ₁ , Xing Yang ₁ , Qin Zhou ₁ , Yimin Jiang ₁ , Xiaochuan Chen ₁

Affiliation

Four anhydrogabosines, (+)‐epoxydon, (–)‐phyllostine, (–)‐RKTS 33, and (–)‐parasitenone, are synthesized from δ‐d‐gluconolactone by two new approaches, which both feature selective sulfonylation and oxirane ring closure on the polyoxygenated aldol cyclization products.

中文翻译：

（+）-环氧树酯，（-）-Phyllostine，（-）-RKTS 33和（-）-对甲硅油酮的特征在于Aldol环化产物的选择性磺酰化和环氧乙烷环封闭的合成

δ- d-葡糖酸内酯通过两种新方法合成了四种脱水葡糖苷，（+）-环氧树酯，（-）-叶芥子碱，（-）-RKTS 33，和（-）-parasitenone，二者均具有选择性磺酰化和环氧乙烷环封闭多氧化羟醛环化产物。

更新日期：2020-07-08

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