Abstract In this study, the continued investigation of a copper (II) complex that yields an extended hydrogen-bonded bilayer framework and it’s ability to include guest molecules, particularly pyridine molecules. Our previous study has shown the ability of this framework to include long-chanined alkyl alcohol molecules and now the copper-based framework has the ability to include pyridine molecules, via non-coordinative and coordinative inclusion. The description of three guest included hydrogen-bonded frameworks that will be discussed: (1) [α-methylbenzylammonium] 2 Cu(PDCA) 2 (H 2 O)·(pyridine), (2) [α-methylbenzylammonium] 2 Cu(PDCA) 2 (H 2 O)·(4-methylpyridine), (3) [α-methylbenzylammonium] 2 Cu(PDCA) 2 (H 2 O)·(4- tert- butylpyridine). The guest included frameworks will be discussed based on X-ray crystallography structures and thermogravimetric analysis data. Graphic Abstract The creation of a hydrogen-bonded metal-organic bilayer framework that allows for coordinative and non-coordinative guest inclusion of pyridine and pyridine derivatives.

中文翻译：

---

吡啶分子客体包含在铜 (II)-双层氢键合金属-有机框架中

摘要 在这项研究中，继续研究铜 (II) 配合物，该配合物可产生扩展的氢键双层框架，并且能够包含客体分子，尤其是吡啶分子。我们之前的研究表明该框架能够包含长链烷醇分子，现在基于铜的框架能够通过非配位和配位包含来包含吡啶分子。三个客体的描述包括将要讨论的氢键骨架：(1) [α-甲基苄基铵] 2 Cu(PDCA) 2 (H 2 O)·(吡啶)，(2) [α-甲基苄基铵] 2 Cu( PDCA) 2 (H 2 O)·(4-甲基吡啶)，(3) [α-甲基苄基铵] 2 Cu(PDCA) 2 (H 2 O)·(4-叔丁基吡啶)。将基于 X 射线晶体学结构和热重分析数据讨论包含的框架。图形摘要创建氢键金属有机双层框架，允许吡啶和吡啶衍生物的配位和非配位客体包含。