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Coordination polymers of Ag(i) and Hg(i) ions with 2,2'-azobispyridine: synthesis, characterization and enhancement of conductivity in the presence of Cu(ii) ions.
Dalton Transactions ( IF 4 ) Pub Date : 2020-06-03 , DOI: 10.1039/d0dt01470b
Suvendu Maity 1 , Kaushik Naskar , Tanmay Bhowmik , Amalendu Bera , Thomas Weyhermüller , Chittaranjan Sinha , Prasanta Ghosh
Affiliation  

The cationic coordination polymers (CPs) of the types [Hg2(abpy)2]n[PF6]2n (1) and [Ag(abpy)]n[PF6]n (2) (abpy = 2,2′-azobispyridine) were synthesized and characterized. Experimentation using the crystals confirmed that 1 and 2 are conductors of electricity. The relative conductivity of 1 is 62 times greater than that of 2. The conductivity of 1 increases 70 fold when it reacts with Cu2+ ions.

中文翻译:

Ag(i)和Hg(i)离子与2,2'-偶氮二吡啶的配位聚合物:在Cu(ii)离子存在下的合成,表征和电导率的提高。

类型为[Hg 2(abpy)2 ] n [PF 6 ] 2 n1)和[Ag(abpy)] n [PF 6 ] n2)(abpy = 2,2)的阳离子配位聚合物(CPs)合成了'-偶氮二吡啶)并进行了表征。使用晶体进行的实验证实了12是电的导体。的相对电导率1比更大的62倍21与Cu 2+离子反应时,电导率1增加70倍。
更新日期:2020-06-29
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