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Palmitic acid functionalization of cellulose fibers for enhancing hydrophobic property
Cellulose ( IF 5.7 ) Pub Date : 2020-04-28 , DOI: 10.1007/s10570-020-03174-x
Soheila Izadyar , Maryam Aghabozorgi , Mohammad Azadfallah

Hydrophobic paper with a static water contact angle (WCA) equal to 140° ± 0.2° has been synthesized by functionalization of the cellulose fibers (CF) with palmitic acid (PA) through layered double zinc and aluminium hydroxides interface (PA-Zn/Al LDH-CF). Different techniques, X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscope (SEM) were used to confirm the grafting of palmitic acid on the cellulose surface. The hydrophobic nature of the PA-Zn/Al LDH-CF was due to the grafting of palmitic acid on the metal hydroxide surfaces which was confirmed by measuring the WCA of the PA-Zn/Al LDH-CF samples. The results showed that using PA-Zn/Al LDH-CF paper can improve the hydrophobic property of cellulose as a renewable material in packaging coatings industry.



中文翻译:

纤维素纤维的棕榈酸官能化以增强疏水性

静态水接触角(WCA)等于140°±0.2°的疏水性纸是通过将纤维素纤维(CF)与棕榈酸(PA)通过层状双锌和氢氧化铝的界面(PA-Zn / Al)官能化而合成的LDH-CF)。使用不同的技术,X射线衍射(XRD),傅里叶变换红外光谱(FTIR)和扫描电子显微镜(SEM)确认棕榈酸在纤维素表面的接枝。PA-Zn / Al LDH-CF的疏水性是由于棕榈酸在金属氢氧化物表面上的接枝,这是通过测量PA-Zn / Al LDH-CF样品的WCA证实的。结果表明,在包装涂料行业中,使用PA-Zn / Al LDH-CF纸可以改善纤维素作为可再生材料的疏水性。

更新日期:2020-04-28
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