Exohedral metallofullerenes are increasingly gaining attention from both academia and industry due to their unique structural and electronic properties. C₆₀ provides an incredible opportunity to bind up to 30 metals on the surface to realize an icosidodecahedral C₆₀@M₃₀ supramolecular complex, the Holy Grail of a coordination saturated buckyball. Recently, the Li and Zhan groups reported a rhombicuboctahedral C₆₀@Cu₂₄ core–shell structure, a giant leap on their journey toward the Holy Grail.

中文翻译：

---

饱和饱和布基球的圣杯之旅

外表面金属富勒烯因其独特的结构和电子特性而越来越受到学术界和工业界的关注。C ₆₀提供了难以置信的机会，可以在表面上结合多达30种金属，从而实现二十碳十面体C ₆₀ @M ₃₀超分子复合物，这是配位饱和布基球的圣杯。最近，Li和Zhan小组报告了菱形八面体C ₆₀ @Cu ₂₄核-壳结构，这是他们朝着圣杯迈进的巨大飞跃。