Copper-catalyzed mild desulfonylation of vinyl sulfonyl molecules,Organic Chemistry Frontiers

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Copper-catalyzed mild desulfonylation of vinyl sulfonyl molecules
Organic Chemistry Frontiers ( IF 5.4 ) Pub Date : 2020-06-02 , DOI: 10.1039/d0qo00468e
Ying Jiang _{1,

2,

3,

4,

5} , Wan-Yin Fang _{1,

2,

3,

4,

5} , K. P. Rakesh _{1,

2,

3,

4,

5} , Hua-Li Qin _{1,

2,

3,

4,

5}

Affiliation

The first Cu-catalyzed chemical selective desulfonylation of vinyl sulfonyl fluorides and vinyl sulfonyl compounds to their corresponding olefins was developed using B₂pin₂–water as the reductant. This protocol featured a wide substrate scope, mild conditions and excellent functional group compatibility.

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