Trifluoromethylthiolation-peroxidation of alkenes using AgSCF₃ and tert-butyl hydroperoxide has been developed in the presence of a copper catalyst. The method exhibits a broad alkene scope with excellent regio- and chemo-selectivities, providing a variety of β-trifluoromethylthio peroxides from readily available materials. In addition, allenes can be applied to deliver the trifluoromethylthiolation-peroxidation products containing a vinyl-SCF₃ moiety.

中文翻译：

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铜催化的烯烃和丙二烯的三氟甲基硫醇化-过氧化

在铜催化剂的存在下，已经开发了使用AgSCF ₃和叔丁基氢过氧化物对烯烃进行三氟甲基硫醇化-过氧化。该方法具有宽泛的烯烃范围，具有出色的区域选择性和化学选择性，可从容易获得的材料中提供多种β-三氟甲硫基过氧化物。另外，丙二烯可用于递送含有乙烯基-SCF ₃部分的三氟甲基硫代化-过氧化产物。