Since early focus on development of the allylation of non‐stabilized enolates, decarboxylative allylation has undergone tremendous evolution. This account describes the progression of decarboxylative allylation within the Tunge group with a focus on efforts to identify and overcome pK_a requirements that initially limited the carboxylates that would undergo decarboxylative allylation.

中文翻译：

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脱羧烯丙基化的演变：克服pKa局限性

自从早期专注于发展非稳定化烯醇化烯丙基化以来，脱羧烯丙基化已经经历了巨大的发展。该说明描述了Tunge组中脱羧烯丙基化的进展，重点是努力确定和克服p K_的要求，_该要求最初限制了将进行脱羧烯丙基化的羧酸盐。