Chiral tertiary phosphines are versatile Lewis base catalysts capable of promoting a wide range of asymmetric reactions. In particular, the recent designed chiral phosphines based on the concept of bi‐/multifunctionality have been demonstrated to be effective catalysts for many types of asymmetric reactions such as (aza)‐MBH reaction/RC reaction, cycloaddition reaction, domino reaction, nucleophilic addition reaction, etc. This review summarizes the recent advances in this field and highlights the selected significant achievements.

中文翻译：

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手性叔膦催化不对称反应

手性叔膦是通用的路易斯碱催化剂，能够促进广泛的不对称反应。特别是，最近基于双/多功能概念设计的手性膦已被证明是许多类型不对称反应的有效催化剂，例如（氮杂）-MBH反应/ RC反应，环加成反应，多米诺反应，亲核加成反应等。这篇综述总结了该领域的最新进展，并重点介绍了选定的重要成就。