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Metal-Organic Coordination Polymers Based on the Anions of Perfluorinated Dicarboxylic Acids
Journal of Structural Chemistry ( IF 0.8 ) Pub Date : 2020-01-08 , DOI: 10.1134/s0022476619120126
A. M. Cheplakova , D. G. Samsonenko , V. P. Fedin

Two new coordination polymers are obtained: layered [Hdabco][Sc2(H20)2(OH)(tFBDC)3]-3/2C4HgO2 (1) (dabco=1,4-diazabicyclo[2.2.2]octane) and chain-like [Zn(CH3OH)4(oFBPDC)]-2CH3OH (2). They are formed by anions of perfluorinated terephthalic (tFBDC2) and biphenyl-4,4'-dicarboxylic (oFBPDC2) acids. The composition and structure of the obtained compounds are determined by the single crystal X-ray diffraction analysis.

中文翻译:

基于全氟二羧酸阴离子的金属有机配位聚合物

获得了两种新的配位聚合物:层状[Hdabco] [Sc 2(H20)2(OH)(tFBDC)3] -3 / 2C4H g O 21)(dabco = 1,4-二氮杂双环[2.2.2]辛烷)和链状[Zn(CH 3 OH)4(oFBPDC)]-2CH 3 OH(2)。它们是由全氟对苯二甲酸(tFBDC 2)和联苯4,4'-二羧酸(oFBPDC 2)的阴离子形成的。所得化合物的组成和结构通过单晶X射线衍射分析确定。
更新日期:2020-01-08
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