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Synthesis of Pyridines and Quinolines by Heterogeneous Catalytic Condensation of Ammonia and Aniline with Glycerol and Its Isopropylidene Derivative
Doklady Chemistry ( IF 0.8 ) Pub Date : 2020-02-01 , DOI: 10.1134/s0012500820020019
A. V. Bayburtli , N. G. Grigorieva , G. Z. Raskil’dina , S. S. Zlotsky , B. I. Kutepov

Abstract Synthesis of pyridines and quinolines by the condensation of ammonia and aniline with glycerol and its isopropylidene derivative on zeolite catalysts with micro- and micro-meso-macroporous structure has been studied for the first time. Effect of processing parameters (temperature, catalyst type, and initial reagent ratio) on product yield (pyridine and a mixture of o - and p -methylpyridines or quinoline and a mixture of o - and p -methylquinolines) has been studied.

中文翻译:

氨苯胺与甘油及其异亚丙基衍生物多相催化缩合合成吡啶和喹啉

摘要 首次研究了氨和苯胺与甘油及其异亚丙基衍生物在具有微孔和微孔结构的沸石催化剂上缩合合成吡啶和喹啉。已经研究了加工参数(温度、催化剂类型和初始试剂比例)对产物产率(吡啶和邻和对甲基吡啶的混合物或喹啉以及邻和对甲基喹啉的混合物)的影响。
更新日期:2020-02-01
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