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Cationic Copolymerization of Cholesterol Vinyl Ether with Methyl Vinyl Sulfide: Towards New Biologically Active Oligomers
Doklady Chemistry ( IF 0.8 ) Pub Date : 2019-12-01 , DOI: 10.1134/s0012500819120036
M. V. Markova , I. V. Tatarinova , K. A. Apartsin , V. V. Kireeva , B. A. Trofimov

Oligomers of cholesterol vinyl ether with methyl vinyl sulfide were synthesized in up to 81% yield (Mn up to 5700) by cationic copolymerization of the indicated monomers in the presence of BF3 ‧ OEt2. The oligomers demonstrate optical activity exceeding that of cholesterol vinyl ether homopolymer.

中文翻译:

胆固醇乙烯基醚与甲基乙烯基硫化物的阳离子共聚:迈向新的生物活性低聚物

在 BF3 ‧ OEt2 存在下,通过指定单体的阳离子共聚,合成了胆固醇乙烯基醚与甲基乙烯基硫醚的低聚物,产率高达 81%(Mn 高达 5700)。低聚物显示出超过胆固醇乙烯基醚均聚物的光学活性。
更新日期:2019-12-01
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