Abstract We present the reaction of a tris(pyrazolyl) beryllium scorpionate (TpBe) complex with a weakly coordinating anion (WCA), which yields the heteroleptic complex TpBeOC(CF3)3 1 (TpBeORF). The product 1 has been characterized by multinuclear NMR spectroscopy (1H, 9Be, 13C) and single-crystal X-ray diffraction (scXRD). Quantum chemical calculations (DFT, NPA, LOL) were performed to study the bonding nature in 1.

中文翻译：

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渴望充电 - 铍蝎复合物如何“吃掉”协调弱的阴离子

摘要 我们介绍了三（吡唑基）蝎形铍 (TpBe) 配合物与弱配位阴离子 (WCA) 的反应，产生了杂配配合物 TpBeOC(CF3)3 1 (TpBeORF)。产物 1 已通过多核 NMR 光谱（1H、9Be、13C）和单晶 X 射线衍射（scXRD）表征。进行了量子化学计算（DFT、NPA、LOL）以研究 1 中的键合性质。