Abstract Despite the favorable NMR-spectroscopic features of the 9Be isotope, the exploration of solid Beryllium compounds by this method has been very limited, owing to safety concerns regarding their preparation and handling. The present review aims to be the first comprehensive one on this topic, summarizing the classical and modern methodologies available for determining the relevant 9Be NMR observables in the solid state. Results on molecular crystals, oxidic materials, and intermetallic systems will be discussed in terms of their informational content in relation to atomic and electronic structure and dynamics, leading to suggestions for future paths of investigation.

中文翻译：

---

铍化合物的固态 Be-9 NMR

摘要 尽管 9Be 同位素具有良好的 NMR 光谱特征，但由于对其制备和处理的安全问题，通过这种方法对固体铍化合物的探索非常有限。本综述旨在成为有关该主题的第一个综合综述，总结了可用于确定相关 9Be NMR 固态观测值的经典和现代方法。分子晶体、氧化材料和金属间化合物系统的结果将根据与原子和电子结构和动力学相关的信息内容进行讨论，从而为未来的研究路径提出建议。