Abstract We have developed a new effective route for obtaining (E)-vinyl-substituted silatranes via ruthenium-catalyzed silylative coupling of 1-allylsilatrane with olefins. Experimental research allowed us also to propose the mechanism of the process based on stoichiometric reactions.

中文翻译：

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1-烯丙基硅杂环烷在钌催化与烯烃的甲硅烷基化偶联中的反应性——机理考虑

摘要 我们开发了一种新的有效途径，通过钌催化的 1-烯丙基硅杂环烷与烯烃的甲硅烷基化偶联获得 (E)-乙烯基取代的硅杂环烷。实验研究还使我们能够基于化学计量反应提出该过程的机理。