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Investigation on Electrochemical Performance of New Flexible Nanocomposite Poly(Vinylidene Fluoride-co-Hexafluoropropylene) Polymer Electrolytes
International Journal of Polymer Science ( IF 3.3 ) Pub Date : 2020-03-23 , DOI: 10.1155/2020/3583806
G. Vijayakumar 1 , A. Maruthadurai 2 , R. Paramasivam 3 , V. Tamilavan 4
Affiliation  

This research paper as an article investigates electrochemical performance of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-co-HFP) flexible nanocomposite polymer electrolytes which have been prepared successfully with incorporation of zinc oxide (ZnO) nanofiller. First, nanofillers are incorporated in a polymer matrix to form the flexible nanocomposite PVdF-co-HFP polymer membranes (PI-CMPM), and it is obtained by phase inversion technique. Contact angles of PI-CMPM have achieved a maximum of 136°. After this procedure, it has been activated by using a 1.0 M LiClO4 containing of DMC/EC (1 : 1 / ratio) electrolyte solution to get flexible nanocomposite polymer electrolytes (PI-CMPE). The optimized PI-CMPM has increased the electrolyte uptake by 150%. It reaches the maximum ionic conductivity value of  S cm−1 at room temperature. Optimized PI-CMPE achieved a maximum transference number of 0.61, which may be further evidence for the ability to fabricate high-performance lithium ion polymer batteries.

中文翻译:

新型柔性纳米复合聚偏氟乙烯-六氟丙烯共聚合物电解质的电化学性能研究

此研究论文作为物品调查聚电化学性能(偏二氟乙烯-共-六氟丙烯)(PVDF--HFP),其已经与氧化锌(ZnO)纳米填料的掺入成功地制备柔性纳米复合聚合物电解质。首先,将纳米填料掺入聚合物基质中以形成柔性纳米复合PVdF- co- HFP聚合物膜(PI-CMPM),并通过相转化技术获得。PI-CMPM的接触角最大为136°。在此过程之后,已通过使用1.0 M LiClO 4将其激活,其中包含DMC / EC(1:1 /比例的电解质溶液以得到柔性纳米复合聚合物电解质(PI-CMPE)。优化的PI-CMPM使电解质吸收增加了150%。达到最大离子电导率值在室温下为 S cm -1。优化的PI-CMPE的最大转移数为0.61,这可能进一步证明了制造高性能锂离子聚合物电池的能力。
更新日期:2020-03-23
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