Site‐selective borylation of simple arenes was realized in one pot via an electrophilic thianthrenation/Pd‐catalyzed borylation sequence. The key to achieve this operatically simple process is the use of Pd catalysis, which could tolerate the solvent and acidic conditions used in the thianthrenation step. This protocol features mild conditions, broad functional group tolerance, and simple manipulations, and is suitable for late‐stage functionalization of a wide range of pharmaceuticals and complex bioactive molecules.

中文翻译：

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钯催化简单的芳烃通过噻吩苯砜化的位点选择性硼化†

简单的芳烃的位点选择性硼化通过亲电子的thththrenation / Pd催化的硼化序列实现。实现这种操作上简单的过程的关键是使用Pd催化，该催化可以耐受在thththrenation步骤中使用的溶剂和酸性条件。该方案具有温和的条件，宽泛的官能团耐受性和简单的操作方法，适用于各种药物和复杂的生物活性分子的后期功能化。