Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9-Phospha- and 9-Arsena-Fluorenium Ions.,Angewandte Chemie International Edition

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Intramolecular Reaction of Transient Phosphenium and Arsenium Ions Giving Rise to Isolable 9-Phospha- and 9-Arsena-Fluorenium Ions.
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2020-05-27 , DOI: 10.1002/anie.202006728
Marian Olaru ₁ , Daniel Duvinage ₁ , Yannik Naß ₁ , Lorraine A Malaspina ₁ , Stefan Mebs ₂ , Jens Beckmann ₁

Affiliation

Transient phosphenium and arsenium ions, generated by fluoride abstraction from bis(m‐terphenyl)fluoropnictogens, underwent intramolecular electrophilic attack prior to methyl group migration and gave rise to isolable 9‐phospha‐ and 9‐arsena‐fluorenium ions.

中文翻译：

瞬态磷和砷离子的分子内反应使上升产生可分离的9-磷和9-Arsena-F离子。

瞬态phosphenium和砷离子，由二氟化物抽象生成（米-三联苯）fluoropnictogens，后行分子内电攻击之前甲基迁移和引起了可分离9- phospha-和9- arsena-fluorenium离子。

更新日期：2020-05-27

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