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Efficient Heterogeneous Palladium-Catalyzed Transfer Hydrogenolysis of Benzylic Alcohols by Formic Acid
Synthesis ( IF 2.6 ) Pub Date : 2020-05-20 , DOI: 10.1055/s-0040-1707398 Samson Afewerki 1 , Armando Córdova 1 , Carlos Palo-Nieto
Synthesis ( IF 2.6 ) Pub Date : 2020-05-20 , DOI: 10.1055/s-0040-1707398 Samson Afewerki 1 , Armando Córdova 1 , Carlos Palo-Nieto
Affiliation
An efficient heterogeneous palladium-catalyzed transfer hydrogenolysis of primary, secondary, and tertiary benzylic alcohols using formic acid as hydrogen source has been developed. The resulting hydrocarbon products were obtained in excellent yields. Moreover, the system exhibits high chemoselectivity, reacting only with the hydroxy groups in the presence of other functional groups, and excellent recyclability.
中文翻译:
甲酸有效异构催化钯醇的转移加氢水解
已经开发了一种有效的多相钯催化的甲酸,伯甲酸和仲苄醇和叔苄醇的转移氢解氢,甲酸为氢源。以优异的产率获得了所得的烃产物。此外,该系统显示出高的化学选择性,在其他官能团存在下仅与羟基反应,并且具有优异的可回收性。
更新日期:2020-05-20
中文翻译:
甲酸有效异构催化钯醇的转移加氢水解
已经开发了一种有效的多相钯催化的甲酸,伯甲酸和仲苄醇和叔苄醇的转移氢解氢,甲酸为氢源。以优异的产率获得了所得的烃产物。此外,该系统显示出高的化学选择性,在其他官能团存在下仅与羟基反应,并且具有优异的可回收性。