Since 1950, when chemiluminescence (CL) of siloxane upon treatment with strong oxidants was discovered by Kurtz, many silicon‐based nanomaterials with different elements, specific molecules, shapes and sizes have been developed as light emitters, energy acceptors, and catalyzers to provide valuable CL and electrogenerated CL (ECL) detection platforms in analytical chemistry fields. This review mainly focuses on the recent development of their mechanisms and sensing methodologies for small molecules, free radicals, ion, enzyme, protein, DNA, cancer cells, and metabolites based on specific reactions such as aptamer sensing and enzymatic reaction. Additionally, the future trend is discussed.

中文翻译：

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基于硅纳米材料的化学发光和电化学发光研究进展。

自1950年以来，库尔兹（Kurtz）发现了用强氧化剂处理后的硅氧烷化学发光（CL），许多具有不同元素，特定分子，形状和大小的硅基纳米材料被开发为发光体，能量受体和催化剂，以提供有价值的分析化学领域中的CL和电生成CL（ECL）检测平台。这篇综述主要关注基于适体传感和酶促反应等特定反应的小分子，自由基，离子，酶，蛋白质，DNA，癌细胞和代谢物的机理和传感方法的最新发展。此外，讨论了未来的趋势。