The first examples of π-(2-fluoroallyl)palladium complexes were synthesized, isolated and characterized including chloride dimers, neutral chloride or cationic triflate complexes bearing PPh₃ or SPhos as the ligands. Preliminary reactivity patterns indicating strong dependence of the chemoselectivity on “hardness” of the nucleophile and the ligand type were studied.

中文翻译：

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（2-氟烯丙基）钯配合物作为Pd催化的Tsuji-Trost 2-氟代烯丙基化反应的中间体：合成和反应性

合成，分离和表征了π-（2-氟烯丙基）钯络合物的第一实例，包括以PPh ₃或SPhos为配体的氯化物二聚体，中性氯化物或阳离子三氟甲磺酸盐络合物。研究表明化学选择性强烈依赖亲核试剂“硬度”和配体类型的初步反应模式。